Tetrahedron Letters p. 6635 - 6638 (1995)
Update date:2022-08-02
Topics:
Gulea-Purcarescu, Mihaela
About-Jaudet, Elie
Collignon, Noel
A diastereoselectivity up to 90percent was achieved in the title rearrangement of lithiated allyloxymethylphosphonates, by using the cheaply available chiral dimenthylphosphonyl ester group as stereodirecting auxiliary.The absolute configuration of the newly formed chiral center was assigned by usual chemical conversions.
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