Tetrahedron p. 11391 - 11426 (1994)
Update date:2022-08-04
Topics:
Clark, David A.
De Riccardis, Francesco
Nicolaou, Kyriacos C.
A strategy is presented for the synthesis of esperamicinone (3), the aglycone of esperamicin A1. The route is based on an asymmetric epoxidation of a quinone monoketal. Two approaches for the installation of the vinylogous urethane are describe
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