Enantioselective Syntheses of D-erythro-Sphingosine and Phytosphingosine from Simple Achiral Aldehydes Using Catalytic Asymmetric Aldol Reactions as Key Steps

DOI: 10.1016/0040-4039(94)88514-1

Source and publish data:

Tetrahedron Letters p. 9573 - 9576 (1994)

Update date:2022-07-30

Topics:

Authors:

Kobayashi, Shu

Hayashi, Takaomi

Kawasuji, Takashi

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Article abstract of DOI:10.1016/0040-4039(94)88514-1

D-erythro-sphingosine and phytosphingosine were prepared from simple achiral aldehydes, trimethylsilylproynal and acrolein, by using chiarl tin(II) Lewis acid-catalyzed asymmetric aldol reactions as key steps.

Full text of DOI:10.1016/0040-4039(94)88514-1

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