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Pd-Catalyzed Cycloaddition of Vinylcyclopentenes with Trimethylenemethane. Substituent Effect on vs Selectively

DOI: 10.1246/cl.1994.2245

Source and publish data:

Chemistry Letters p. 2245 - 2248 (1994)

Update date:2022-08-05

Topics:

Authors:

Trost, Barry M.Trost, Barry M.

Yamazaki, ShokoYamazaki, Shoko

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Article abstract of DOI:10.1246/cl.1994.2245

The Pd-catalyzed reaction of 2-vinylcyclopentenes 2 and 3 with trimethylenemethane gave <4+3> and <3+2> cycloadducts.Derivatization of 2-vinylcyclopentenones with bulky ketal substituents served to enhance seven-membered ring formation.

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Full text of DOI:10.1246/cl.1994.2245

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