Journal of the Chemical Society, Dalton Transactions p. 177 - 180 (1995)
Update date:2022-08-04
Topics:
Schulz, Stephan
Roesky, Herbert W.
Noltemeyer, Mathias
Schmidt, Hans-Georg
The reaction of AlCl3 with Li(OR')*Et2O (R' = C6H2-(t-Bu3)-2,4,6) in diethyl ether gave Al(OR')Cl2*Et2O 1, a monomeric aryloxide compound of aluminium.Its reaction with 2 equivalents of potassium gave elemental aluminium and a four-membered Al2O2 ring.Compound 1 crystallizes in the monoclinic space group P21/c with a = 10.692(2), b = 21.825(4), c = 11.683(2) Angstroem and β = 115.49(3) deg and compound 2 in the space group P<*> with a = 10.227(2), b = 10.966(2), c = 18.493(4) Angstroem, α = 101.13(3), β = 97.63(3) and γ = 115.29(3) deg.
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