
Tetrahedron Letters p. 8141 - 8144 (1994)
Update date:2022-08-04
Topics:
Bunnelle, William H.
Lee, Sang-Gi
The geometries of the carbonyl oxides produced during ozonolysis of E- and Z-vinyl ethers have been assigned using the intramolecular trapping method. The alkoxy substituent exerts an anti-directive effect on formation of the carbonyl oxide; that is, the carbonyl oxide has a geometry opposite to that of the precursor vinyl ether.
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