
Tetrahedron Letters p. 8635 - 8638 (1994)
Update date:2022-08-03
Topics:
Suginome, Michinori
Kinugasa, Hiroshi
Ito, Yoshihiko
Intramolecular cyanosilylation was achieved by the reaction of chlorodiphenylsilyl ether of homopropargylic alcohols with trimethylsilylcyanide in the presence of palladium catalyst. The reaction proceeded regio- and stereoselectively to give (Z)-3-(1-cya
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