Palladium-Catalyzed Intramolecular Cyanosilylation of Alkynes Leading to Stereoselective Synthesis of α,β-Unsaturated Nitriles

DOI: 10.1016/S0040-4039(00)78457-7

Source and publish data:

Tetrahedron Letters p. 8635 - 8638 (1994)

Update date:2022-08-03

Topics:

Authors:

Suginome, Michinori

Kinugasa, Hiroshi

Ito, Yoshihiko

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Article abstract of DOI:10.1016/S0040-4039(00)78457-7

Intramolecular cyanosilylation was achieved by the reaction of chlorodiphenylsilyl ether of homopropargylic alcohols with trimethylsilylcyanide in the presence of palladium catalyst. The reaction proceeded regio- and stereoselectively to give (Z)-3-(1-cya

Full text of DOI:10.1016/S0040-4039(00)78457-7

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