Preparation of Monomeric Neutral or Anionic Tris(polyfluorophenyl)thallium(III) and of Anionic Heteronuclear Tris(polyfluorophenyl)thallium-Metal Carbonyl Complexes

DOI: 10.1039/DT9830001127

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1127 - 1130 (1983)

Update date:2022-08-03

Topics:

Authors:

Uson, Rafael

Laguna, Antonio

Abad, J. Antonio

Jesus, Ernesto de

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9830001127

The complex (diox= 1,4-dioxan) has been prepared by the reaction of TlCl3 with LiR (R= 2,4,6-C6F3H2), or of with HBF4 (R= C6F5) and subsequent addition of dioxan.The displacement of dioxan by (a) neutral ligands leads to (L= OPPh3, pyridine, PPh3, or Ph2PCH2PPh2); (b) anionic ligands affords Q (+) or (+); X= Cl(-), CN(-), NO3(-), or CF3CO2(-)>; and (c) metal carbonylate gives Q (-) (cp= η-C5H5), (-), (-) or (-)>.

Full text of DOI:10.1039/DT9830001127

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[N(PPh₃)2][Tl(2,4,6-C₆F₃H₂)3Cl]

Cas No:88152-26-5

R&D Labs maybe for 88152-26-5

ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
SHANDONG QINGYUNCHANGXIN CHEMICAL SCIENCE-TECH CO.,LTD

Contact:86-21-60560171

Address:1689Donghuan Rade,Qingyun County, Dezhou City, Shandong,China
Shijiazhuang City Xiehe Pharmaceutical Co., Ltd

Contact:+86-311-80817929

Address:Shangzhuang,Shijiazhuang,China
Shijiazhuang Frontierchem Co., Ltd.

Contact:+86-311-89271196

Address:4-4-202 No.15 Biandian Street,Shijiazhuang

Relevant to this article

Synthesis and characterization of cyclopentadienone-annelated hexadehydrodibenzo[12]annulene

Doi:10.1246/cl.2006.168
(2006)
CYCLOADDITION REACTION OF N-IMIDOYL SULFOXIMIDES WITH DIPHENYLCYCLOPROPENONE TO YIELD PYRIMIDINONE OR PYRROLINONE DERIVATIVES.

Doi:10.1246/bcsj.56.2438
(1983)
Synthesis of C-Functionalized trans-Cyclohexyldiethylenetriaminepenta-acetic Acids for Labelling of Monoclonal Antibodies with the Bismuth-212 α-Particle Emitter

Doi:10.1039/P19920001173
(1992)
Novel reactivities on tert-butyldimethylsilyl and tert-butyldiphenylsilyl ethers; Application to the synthesis of 11-epi-PGF(2α)

Doi:10.1248/cpb.31.2607
(1983)
Species differences in metabolism of sodium 2-[4-(2-oxocyclopentylmethyl)-phenyl]propionate dihydrate (loxoprofen sodium), a new anti-inflammatory agent

Doi:10.1248/cpb.31.3656
(1983)
Ferroelectric-like behaviour of the SmCP phase in liquid crystalline compounds with asymmetrical bent-core molecules

Doi:10.1039/b601084a
(2006)

Article Doi