Preparation of Monomeric Neutral or Anionic Tris(polyfluorophenyl)thallium(III) and of Anionic Heteronuclear Tris(polyfluorophenyl)thallium-Metal Carbonyl Complexes

DOI: 10.1039/DT9830001127

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1127 - 1130 (1983)

Update date:2022-08-03

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Authors:

Uson, Rafael

Laguna, Antonio

Abad, J. Antonio

Jesus, Ernesto de

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Article abstract of DOI:10.1039/DT9830001127

The complex (diox= 1,4-dioxan) has been prepared by the reaction of TlCl3 with LiR (R= 2,4,6-C6F3H2), or of with HBF4 (R= C6F5) and subsequent addition of dioxan.The displacement of dioxan by (a) neutral ligands leads to (L= OPPh3, pyridine, PPh3, or Ph2PCH2PPh2); (b) anionic ligands affords Q (+) or (+); X= Cl(-), CN(-), NO3(-), or CF3CO2(-)>; and (c) metal carbonylate gives Q (-) (cp= η-C5H5), (-), (-) or (-)>.

Full text of DOI:10.1039/DT9830001127

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