Enantioselective synthesis of α-branched α-hydroxy ketones via chiral N-sulfonyl-2-alkyl-2-cyano-1,3-oxazolidines

DOI: 10.1016/0040-4039(94)85315-0

Source and publish data:

Tetrahedron Letters p. 7365 - 7368 (1994)

Update date:2022-08-05

Topics:

Authors:

Harder, Timm

Loehl, Thorsten

Bolte, Michael

Wagner, Kerstin

Hoppe, Dieter

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Article abstract of DOI:10.1016/0040-4039(94)85315-0

The stereochemically homogeneous title compounds 6, prepared with two steps from orthoesters and N-tosyl-phenylglycinol 4, afford with two sequential Grignard additions predominantly the tertiary alcohols 8. Electrochemical detosylation, followed by aqueo

Full text of DOI:10.1016/0040-4039(94)85315-0

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Product name:2-Oxazolidinecarbonitrile, 2-methyl-3-[(4-methylphenyl)sulfonyl]-4-phenyl-, (2S,4R)-

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