Asymmetric Synthesis of the Hydroxylamino Sugar of Calicheamicin

DOI: 10.1016/S0040-4039(00)73286-2

Source and publish data:

Tetrahedron Letters p. 4935 - 4938 (1994)

Update date:2022-07-29

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Authors:

Roush, William R.

Follows, Bruce C.

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Article abstract of DOI:10.1016/S0040-4039(00)73286-2

A stereochemically general procedure for the conversion of 2,3-epoxyalcohols to N-alkoxy oxazolidinones via the DBU promoted cyclizations of 2,3-epoxy-N-alkoxyurethanes has been developed and applied to the first asymmetric synthesis of the calicheamicin

Full text of DOI:10.1016/S0040-4039(00)73286-2

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