Preparation of Homochiral Crown Ether containing (S)-1-(1-Adamantyl)ethane-1,2-diol as a Chiral Subunit and its Enantioselective Complexation with an Organic Ammonium Cation

DOI: 10.1016/0957-4166(94)80125-8

Source and publish data:

Tetrahedron Asymmetry p. 1549 - 1558 (1994)

Update date:2022-08-03

Topics:

Authors:

Naemura, Koichiro

Mizo-oku, Takashi

Kamada, Kimiko

Hirose, Keiji

Tobe, Yoshito

et al. et al.

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Article abstract of DOI:10.1016/0957-4166(94)80125-8

Homochiral 1-(1-adamantyl)ethane-1,2-diol (5) was prepared and its absolute configuration was determined to be (S)-(+)-5 by enzymatic and 1H n.m.r. spectroscopic methods.Using (S)-(+)-5 as a chiral subunit, the homochiral crown ether (+)-18 was synthesize

Full text of DOI:10.1016/0957-4166(94)80125-8

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