Photochemical Generation of 16-Electron 5-C5H5)(PMe3)> and 5-C5H5)(PMe3)> in Low-temperature Matrices: Evidence for Methane Activation

DOI: 10.1039/DT9940003519

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3519 - 3526 (1994)

Update date:2022-08-03

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Authors:

Partridge, Martin G.

McCamley, Andrew

Perutz, Robin N.

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Article abstract of DOI:10.1039/DT9940003519

The photochemical reactions of 5-C5H5)(PMe3)(H)2> and 5-C5H5)(PMe3)(H)2> have been studied in Ar, CH4, N2 and CO-doped argon matrices by IR and UV/VIS spectroscopy.The UV photolysis in argon matrices results in the formatio

Full text of DOI:10.1039/DT9940003519

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