Tetrahedron Letters p. 7993 - 7996 (1994)
Update date:2022-08-02
Topics:
Hatakeyama, Susumi
Kawamura, Mitsuhiro
Takano, Seiichi
Irie, Hiroshi
The first total syntheses of (+)-paeonilactone C and (+)-paeoniflorigenone, representative monoterpenes of Paeoniae Radix, have been accomplished starting with R-(-)-carvone via lipase catalyzed highly diastereoselective enzymatic acetylation.The latter synthesis also means the first total synthesis of (+)-paeonisuffral, a new monoterpene recently isolated from Moutan Cortex.
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