Tetrahedron Asymmetry p. 1409 - 1418 (1995)
Update date:2022-08-04
Topics: Synthesis β-Amino Acids β-Lactams Conformationally constrained α,α-disubstituted Enantiomerically pure form
Avenoza
Cativiela
Paris
Peregrina
Optically active cis-, 8a and 8b, and trans-1-aminomethyl-2-phenylcyclohexane-1-carboxylic acids, 9a and 9b, were obtained starting from 1,3-butadiene using Diels-Alder cycloadditions with chiral (E)-2-cyanocinnamates as key steps and following a protocol
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Doi:10.1039/DT9940002113
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