Stereoselective synthesis of the epimeric Δ7-tetrahydrocannabinols

DOI: 10.1016/0040-4020(94)00995-7

Source and publish data:

Tetrahedron p. 1017 - 1032 (1995)

Update date:2022-07-30

Topics: Synthesis Stereoselective Epimeric

Authors:

Huffman, John W.

Kenneth Banner

Zoorob, Grace K.

Howard Joyner

Reggio, Patricia H.

Martin, Billy R.

Compton, David R.

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Article abstract of DOI:10.1016/0040-4020(94)00995-7

Both C9 epimers of Δ⁷-HTC (3 and 4) have been synthesized from Δ⁸-THC methyl ether (12). Hydroboration of 12 gave a mixture of stereoisomeric 8-hydroxyhexahydrocannabinols. The 8α-ol was converted into the 9β-methyl epimer (4) of Δ View More

Full text of DOI:10.1016/0040-4020(94)00995-7

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