Journal of Organic Chemistry p. 2506 - 2513 (1995)
Update date:2022-08-04
Topics: Synthesis Chiral Chemoenzymatic approach Enantioselective synthesis Experimental Approach
Danieli, Bruno
Lesma, Giordano
Mauro, Marina
Palmisano, Giovanni
Passarella, Daniele
(-)-Akagerine (1) was synthesized in an efficient and stereocontrolled fashion from the readily available (1S,2R)-cyclohexenedimethanol monoacetate 4.Key steps were the cleavage of the C(17)/C(18) bond of a 14a and the regio- and stereoselective cyclizati
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