Chemistry Letters p. 2143 - 2146 (1994)
Update date:2022-08-05
Topics:
Hayashi, Nobuyuki
Mine, Takaaki
Fujiwara, Kenshu
Murai, Akio
Construction of the tetrahydrofuran ring part of polycavernoside A, which has been isolated as one of toxic principles from the red alga Polycavernosa tsudai, is described starting from 2,2-dimethylpropane-1,3-diol.The synthesis involves the Sharpless epoxidation and the Evans procedure for introduction of the three chiral centers.
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