Katsuki-Sharpless Asymmetric Epoxidation of Alkenylethylene Glycols: the Origin of Inverted Stereoselection

DOI: 10.1039/c39940002197

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2197 - 2200 (1994)

Update date:2022-08-05

Topics:

Authors:

Yoshimitsu, Takehiko

Ogasawara, Kunio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940002197

The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti2(tartrate)2 complex.

Full text of DOI:10.1039/c39940002197

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:D-threo-Pentitol, 1,2-anhydro-4,5-dideoxy-2-C-ethynyl- (9CI)

Cas No:163259-76-5

R&D Labs maybe for 163259-76-5

Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Zibo Kunran Enterprises Co. LTD

website:http://www.kunranchem.com

Contact:0086 533 5200669

Address:No. 96 Jinjing Avenue, Zibo, Shandong, China
Wuhan Chemwish Technology Co., Ltd

website:http://www.chemwish.com/

Contact:+86-27-67849912

Address:Room 1311, Unit 2, Block1, Innovation Road East Lake High-tech Development Zone Wuhan, Hubei，P.R. China
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
GBXF SILICONES CO.,LTD

website:http://www.gbxfsilicones.com/

Contact:86-25-68900673

Address:He Country Provincial Fine Chemical Industrial Park of Chaohu city,Anhui province,China

Relevant to this article

Synthesis and characterization of n-substituted (S)-1,2,3,4-tetrahydroisoquinoline-3-carboxamides and thioamides as organocatalysts for asymmetric aldol reaction

Doi:10.3987/COM-14-13029
(2014)
Discovery of Hydrolysis-Resistant Isoindoline N -Acyl Amino Acid Analogues that Stimulate Mitochondrial Respiration

Doi:10.1021/acs.jmedchem.8b00029
(2018)
Bis[3-(3,5-dialkyl-4-hydroxyphenyl)propyl]monoand disulfides as the sevilen stabilizers

Doi:10.1134/S1070363211060144
(2011)
Design and Synthesis of 1-Heteroaryl-3-(1-benzyl-4-piperidinyl)propan-1-one Derivatives as Potent, Selective Acetylcholinesterase Inhibitors

Doi:10.1021/jm00007a005
(1995)
Practical methods for the synthesis of trifluoromethylated alkynes: Oxidative trifluoromethylation of copper acetylides and alkynes

Doi:10.1002/adsc.201400057
(2014)
Stereoselectivity Inversion by Water Addition in the ?SO3H-catalyzed Tandem Prins-Ritter Reaction for Synthesis of 4-amidotetrahydropyran Derivatives

Doi:10.1002/cctc.202000070
(2020)

Article Doi