Katsuki-Sharpless Asymmetric Epoxidation of Alkenylethylene Glycols: the Origin of Inverted Stereoselection

DOI: 10.1039/c39940002197

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2197 - 2200 (1994)

Update date:2022-08-05

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Authors:

Yoshimitsu, Takehiko

Ogasawara, Kunio

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Article abstract of DOI:10.1039/c39940002197

The Katsuki-Sharpless asymmetric epoxidation of linear and cyclic alkenylethylene glycols has led to a conclusion that the origin of the inverted stereoselection is due to the simultaneous coordination between both hydroxy groups of the glycol substrates and both titanium atoms in the Ti2(tartrate)2 complex.

Full text of DOI:10.1039/c39940002197

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