Chemistry of μ-η1:η2α,β-Butadiynyls: Chain Extension on C4 Polycarbon Ligands

DOI: 10.1039/c39950002165

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2165 - 2166 (1995)

Update date:2022-08-05

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Authors:

Blenkiron, Peter

Pilette, Didier

Corrigan, John F.

Taylor, Nicholas J.

Carty, Arthur J.

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Article abstract of DOI:10.1039/c39950002165

The binuclear butadiynyl compounds Ru2(CO)6(μ-η¹,η²_α,β-CC-CCR)(μ-PPh2) (R = Bu^t 1a or 1b), with one ?-coordinated and one free triple bond, synthesised via thermolysis of Ru3(CO)11(PPh2CC-CCR), react with NEt2H

Full text of DOI:10.1039/c39950002165

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Product name:[Ru₃(CO)11(P(C₆H₅)2CCCCC(CH₃)3)]

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