Hydrodesulfurization (HDS) model systems. Opening, hydrogenation, and hydrodesulfurization of dibenzothiophene (DBT) at iridium. First case of catalytic HDS of DBT in homogeneous phase

DOI: 10.1021/om00005a035

Source and publish data:

Organometallics p. 2342 - 2352 (1995)

Update date:2022-07-30

Topics:

Authors:

Bianchini, Claudio

Victoria Jiménez

Meli, Andrea

Moneti, Simonetta

Vizza, Francesco

Herrera, Verónica

Sánchez-Delgado, Roberto A.

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Article abstract of DOI:10.1021/om00005a035

The kinetic selectivity for C-H vs C-S activation of dibenzothiophene (DBT) by the [(triphos)IrH] fragment has been observed upon either thermolysis of (triphos)Ir(H)₂(C₂H₅) in THF in the temperature range from 70 to 160°C

Full text of DOI:10.1021/om00005a035

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