A stereoselective approach to the angucyclinone antibiotics: A total synthesis of the C-1 epimer of (±)-rubiginone B1

DOI: 10.1016/S0040-4039(00)91799-4

Source and publish data:

Tetrahedron Letters p. 1373 - 1376 (1993)

Update date:2022-07-29

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Authors:

Larsen Larsen

O'Shea O'Shea

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Article abstract of DOI:10.1016/S0040-4039(00)91799-4

A stereoselective Lewis acid-promoted cycloaddition reaction of 5-hydroxy-1,4-naphthoquinone and dienol (12) gave a key intermediate (14) which was transformed into the title compound (18) in 35% overall yield.

Full text of DOI:10.1016/S0040-4039(00)91799-4

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