Welcome to LookChem.com Sign In|Join Free

Article Doi

Homo- and Hetero-dinuclear Complexes of Palladium and Platinum containing Phosphinoacetylene and/or Chloride as Bridging Ligands

DOI: 10.1039/DT9950001333

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1333 - 1340 (1995)

Update date:2022-07-29

Topics:

Authors:

Fornies, JuanFornies, Juan

Lalinde,ElenaLalinde,Elena

Martin, AntonioMartin, Antonio

Moreno, M. TeresaMoreno, M. Teresa

Welch, Alan J.Welch, Alan J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001333

Reactions between the diphenylacetylenephosphine complexes cis-CR)2> (M' = Pt or Pd, R = Ph or t-Bu) and cis- (M = Pt or Pd; thf = tetrahydrofuran) in a 1:1 molar ratio have been studied.Three types of products have been obtained: (a) asymmetric homo- and hetero-dinuclear complexes gem-<(C6F5)2M(μ-Cl)2M'(PPh2C<*>CR)2>, (b) symmetric trans-palladium derivatives <CR)>2> and (c) the unusual chloride and diphenyl(phenylethynyl)phosphine bridged dinuclear compounds <(C6F5)2Pt(μ-PPh2C<*>CPh)M'Cl(PPh2C<*>CPh)>.The complexes have been characterised by microanalysis, IR and NMR spectroscopy and the molecular structure of <(C6F5)2Pt(μ-Cl)(μ-PPh2C<*>CPh)PtCl(PPh2C<*>CPh)>*OC4H8.The NMR spectral data (1H, 19F and 31P) indicate that, in solution, mixtures of isomers <(C6F5)2Pt(μ-Cl)2M'(PPh2C<*>CR)2 and <(C6F5)2Pt(μ-Cl)(μ-PPh2C<*>CPh)M'Cl(PPh2C<*>CPh)> are present.

View More

Products guided by the article

Product name:gem-[(C6F5)2Pd(μ-Cl)2Pd(PPh2C.tplbond.CPh)2]

Cas No:164078-15-3

164078-15-3

R&D Labs maybe for 164078-15-3

Relevant to this article

Hot Product