Intramolecular Cyclizations of α-Stannyl Radicals to Acylsilanes: Regiospecific Syntheses of Five-membered Cyclic Silyl Enol Ethers

DOI: 10.1039/c39950000981

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Journal of the Chemical Society. Chemical communications p. 981 - 982 (1995)

Update date:2022-08-04

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Authors:

Tsai, Yeun-Min

Chang, Sheng-Yueh

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Article abstract of DOI:10.1039/c39950000981

α-Stannyl radicals generated from acylsilanes 5, 13 and 14 cyclize to give good yields of cyclic silyl enol ethers after sequential cyclizations, radical Brook rearrangements and β-scissions.

Full text of DOI:10.1039/c39950000981

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