Journal of Organometallic Chemistry p. 133 - 142 (1995)
Update date:2022-09-26
Topics:
Mueller, Thomas
Apeloig, Yitzhak
Hemme, Ina
Klingebiel, Uwe
Noltemeyer, Mathias
The bis(silylamino)difluorosilane (RHN)2SiF2, 1, and the (silylamino)-trifluorosilane (RHN)SiF3 with R = tBu2PhSi, 2, were prepared by reaction of lithiated di-tert-butylphenylsilylamine with tetrafluorosilane.Reaction of 1 with two molar equivalents of tBuLi yields the dilithiated 3, which when brought into reaction with SiF4, gives the tetrafluoro-substituted four-membered (SiNSiN) ring species
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Doi:10.1016/0022-328X(95)05450-4
(1995)Doi:10.1021/om00009a015
(1995)Doi:10.1002/jhet.720
(2012)Doi:10.1021/ja00154a002
(1995)Doi:10.1055/s-0035-1562438
(2016)Doi:10.1021/jo00118a005
(1995)