Oxidative Addition of Diorganyl Ditellurides to Mn(CO)5(1-): Crystal Structure of cis-[Na-18-crown-6-ether.2THF][Mn(CO)4(TePh)2], [PPN][(CO)3Mn(μ-TePh)3Mn(CO)3], (CO)3Mn(μ-TePh)3Co(CO)(μ-TePh)2Mn(CO)4, and (CO)4Mn(μ-TePh)2Mn(CO)4

Article abstract of DOI:10.1021/ic00118a023

Oxidative addition of diphenyl ditellurides to organometallic fragment [Mn(CO)5](1-) produced cis-[Mn(CO)4(TePh)2](1-). This complex crystallized in monoclinic space group P21/n with a = 12.876(6) ?, b = 18.001(7) ?, c = 18.670(7) ?, β = 93.77(3)°, V = 43