Ligand Substitution in and the Isomerism of

DOI: 10.1039/DT9950001791

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1791 - 1798 (1995)

Update date:2022-08-03

Topics:

Authors:

Lin, Jiann T.

Chou, Yung Chun

Shih, Yeh E.

Hong, Fong E.

Wen, Yuh S.

et al. et al.

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Article abstract of DOI:10.1039/DT9950001791

Treatment of with NO(1+)BF4(1-) provided 1.Several phosphide-bridged diiron complexes, (R = Me 2, OMe 3 or Ph 4), 5-C5H4PPh2)2Fe 14> and 3(NO)(μ-PPh2)> 15, have been derived from ligand substitution in 1.These complexes exhibit structural versatility.Interconversion between two isomers of 5, 5b and 5c, has been established by variable-temperature 31P- NMR, two-dimensional exchange spectroscopy and single-crystal structure determination.

Full text of DOI:10.1039/DT9950001791

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Product name:Fe(CO)3((η5-C5H4PPh2)2Fe)(μ-PPh2)Fe(CO)(NO)

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