Towards conformationally dependent redox-responsive molecular switches. New polyferrocene bis benzo crown ether receptors

DOI: 10.1016/0022-328X(94)05191-D

Source and publish data:

Journal of Organometallic Chemistry p. 143 - 148 (1995)

Update date:2022-09-26

Topics:

Authors:

Beer, Paul D.

Crane, Christopher G.

Danks, Jonathan P.

Gale, Philip A.

McAleer, Jerome F.

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Article abstract of DOI:10.1016/0022-328X(94)05191-D

New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation.Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations. Keywords: Iron; Polyferrocene; Crown ethers; Molecular switches; Redox couples; Potassium complexes

Full text of DOI:10.1016/0022-328X(94)05191-D

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