
Journal of Organometallic Chemistry p. 143 - 148 (1995)
Update date:2022-09-26
Topics:
Beer, Paul D.
Crane, Christopher G.
Danks, Jonathan P.
Gale, Philip A.
McAleer, Jerome F.
New polyferrocene bis benzo-15-crown-5 ligands have been prepared and shown to form 1:1 intramolecular sandwich complexes with the potassium cation.Electrochemical investigations reveal that both receptors undergo small anodic perturbations of the respective ferrocene-ferrocenium redox couples in the presence of alkali metal cations. Keywords: Iron; Polyferrocene; Crown ethers; Molecular switches; Redox couples; Potassium complexes
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