Helvetica Chimica Acta p. 670 - 678 (1995)
Update date:2022-08-03
Topics:
Saady, Mourad
Lebeau, Luc
Mioskowski, Charles
Benzyl phosphites were used in the Michaelis-Arbuzov reaction.Special experimental conditions allowed preparation of a set of phosphonate analogs of mono-, di-, and triphosphate.Furthermore, regioselective mono-deprotection mades these molecules useful building blocks for the synthesis of analogs of polyphosphorylated compounds of biological interest (e.g. nucleotides), after removal of all phosphonate benzyl ester groups under very mild conditions and high yields.
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