Synthesis and Structure of Bis(phosphaallyl) Complexes with Two-co-ordinate Phosphorus

DOI: 10.1039/DT9950001951

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1951 - 1956 (1995)

Update date:2022-08-03

Topics:

Authors:

Wirringa, Uwe

Voelker, Heike

Roesky, Herbert W.

Shermolovich, Yuri

Markovski, Leonid

et al. et al.

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Article abstract of DOI:10.1039/DT9950001951

The compound was prepared and its crystal structure determined.It is one of the rare examples of non-symmetrically substituted cyclophosphazanes.A series of bis- and mono-phosphaallyl complexes (M = Zn or Cd), , , (R' = t-Bu or adamantyl) and have been prepared from cyclic aminophosphazanes and aminoiminophosphanes.The structure of the spirocyclic bis(1,3-diaza-2-phosphaallyl)zinc complex (R = R' = C6H3(i-Pr)2-2,6) was determined.

Full text of DOI:10.1039/DT9950001951

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