Journal of the Chemical Society. Chemical communications p. 1157 - 1158 (1995)
Update date:2022-07-30
Topics:
Schaefer, Annemarie
Weidenbruch, Manfred
Saak, Wolfgang
Pohl, Siegfried
Bis(2,4,6-triisopropylphenyl)stannylene, formed by thermolysis of the cyclotristannane 4, reacts with 4,5-dimethyl-1,3-diisopropylimidazol-2-ylidene to furnish the adduct 8; an X-ray structural analysis of this compound reveals the presence of a long tin-carbon 'double bond' with a length of 237.9(5) pm and a distinctly pyramidal tin centre.
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Doi:10.1016/S0960-894X(99)00500-4
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(1999)Doi:10.1002/ejoc.200800629
(2008)Doi:10.1007/s11172-012-0024-7
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