A Carbene-Stannylene Adduct with a Long Tin-Carbon Double Bond?

DOI: 10.1039/C39950001157

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1157 - 1158 (1995)

Update date:2022-07-30

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Authors:

Schaefer, Annemarie

Weidenbruch, Manfred

Saak, Wolfgang

Pohl, Siegfried

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Article abstract of DOI:10.1039/C39950001157

Bis(2,4,6-triisopropylphenyl)stannylene, formed by thermolysis of the cyclotristannane 4, reacts with 4,5-dimethyl-1,3-diisopropylimidazol-2-ylidene to furnish the adduct 8; an X-ray structural analysis of this compound reveals the presence of a long tin-carbon 'double bond' with a length of 237.9(5) pm and a distinctly pyramidal tin centre.

Full text of DOI:10.1039/C39950001157

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