Enhanced Slip Distortions in 1-Phenyl-2-methyldicarbaplatinaboranes. Conformational Destabilisation in the Isomerisation of 1-Phenyldicarbaplatinaboranes

DOI: 10.1039/DT9950001755

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1755 - 1764 (1995)

Update date:2022-08-05

Topics:

Authors:

McGrath, Thomas D.

Welch, Alan J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001755

The compounds Tl2<7-Ph-8-Me-7,8-nido-C2B9H9>, <7-Ph-8-Me-7,8-nido-C2B9H10>, 1-Ph-2-Me-3,3-L₂-3,1,2-PtC2B9H9 have been prepared and characterised.The platinum complexes were obtained from the reactions between Tl2<7-Ph-8-Me-7,8-nido-C2B9H9> and the appropriate species.Crystallographic studies upon the compounds where L = PEt3 and two crystalline modifications of that where L = PPh3 afforded evidance of a substantial influence of intramolecular crowding upon the observed structures, so that the lateral slippage (Δ) of the metal fragment is significantly enhanced: Δ = 0.74 and 0.94 and 0.91 Angstroem respectively.These compounds do not isomerise under conditions which produce rearrangement in the corresponding (less-congested) derivatives of 1-phenylcarbaborane, consistent with the proposed conformational destabilisation in the latter system.

Full text of DOI:10.1039/DT9950001755

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:1-Ph-2-Me-3,3-(PPh₃)2-3,1,2-PtC₂B₉H₉

Cas No:167173-06-0

R&D Labs maybe for 167173-06-0

Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
Liaoyang Xinyou Chemical Products Co.,Ltd.

Contact:+86-419-5165433 13604191870

Address:Huishang Road6-1, Hongwei District, Liaoyang, Liaoning, China
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
ZK Biochem Group Co., Ltd

Contact:+86-532-80762375

Address:No. 6, Hongkong Middle Road, Qingdao, China

Relevant to this article

Nucleophilic Additions to the Chiral Rhenium Alkene Complexes 5-C5H5)(NO)(PPh3)(H2C=CHR)>BF4 (R = H, Me, CH2CH2Me, Ph or CH2Ph): Regio-, Diastereo- and Enantio-selectivities

Doi:10.1039/DT9950001857
(1995)
Reaction of N-halosulfonamide. IV. A cleavage reaction of ether with N,N-dihalobenzenesulfonamide. (1).

Doi:10.1248/cpb.15.1331
(1967)
Doi:10.1039/j39670002700
(1967)
Doi:10.1016/S0040-4039(00)72432-4
(1973)
An improved synthesis and resolution of (±)-cis,cis-2,2'-spirobiindane-1,1'-diol

Doi:10.1016/0957-4166(95)00201-Y
(1995)
Nonpeptide GPIIb/IIIa inhibitors. 16. Thieno[2,3-b]thiophene α-sulfonamides are potent inhibitors of platelet aggregation

Doi:10.1016/S0960-894X(97)00120-0
(1997)

Article Doi