Tetrahedron Asymmetry p. 505 - 518 (1995)
Update date:2022-07-29
Topics:
Simons
Wang
Heinz
Giger
Mallat
Pfaltz
Baiker
A series of enantiomerically pure chiral amino alcohols have been synthesized and applied as modifiers in the enantioselective hydrogenation of ethyl pyruvate over supported Pt catalysts. Their use enabled an enantiomeric excess of up to 75%. A molecular modelling study of the modifiers and reactant on a Pt(111) surface provides explanation for the observed enantiodifferentiation.
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(1968)
