Highly functionalized enantiopure oxatricyclo[3.3.1.04,6]nonanes; Selective opening of an activated cyclopropane ring

DOI: 10.1016/S0040-4039(96)02182-X

Source and publish data:

Tetrahedron Letters p. 9187 - 9188 (1996)

Update date:2022-08-03

Topics:

Authors:

Braun, Norbert A.

Spitzner, Dietrich

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Article abstract of DOI:10.1016/S0040-4039(96)02182-X

Baeyer-Villiger oxidation of 3 gives solely the lactones 4. The double-pull-push substituted cyclopropane moiety of 4b is selectively opened upon hydrogenolysis of the benzyl ether to yield ketone 5.

Full text of DOI:10.1016/S0040-4039(96)02182-X

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