Journal of the Chemical Society, Dalton Transactions p. 2067 - 2072 (1995)
Update date:2022-08-05
Topics:
Raubenheimer, Helgard G.
Desmet, Mieke
Kruger, Gert J.
Isothiazolyl complexes have been synthesized by the addition of isothiazol-5-yllithium to gold(I) chloride or tetrahydrothiophene(pentafluorophenyl)gold complexes.Protonation or alkylation of these isothiazolyl complexes yielded the corresponding isothiazolinylidene complexes.The mono(isothiazolyl)-aurate and mono(isothiazolinylidene) complexes undergo homoleptic rearrangement.The molecular structure of the mono(isothiazolyl) complex
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