Selective Formation of Four-Membered Metallacyclic Pt-N-P-C Compounds from Reactions of Bis((N-arylimino)phosphoranyl)methanes with Halide-Bridged Platinum(II) Phosphine Dimers. X-ray Crystal Structures of [PtCl(PMe2Ph){CH(PPh2=NC6H4-4-CH3)(PPh2NHC6H4-4-C

Article abstract of DOI:10.1021/ic00120a013

Bridge-splitting reactions of Pt2X4(PR3)2 (X = Cl, Br; PR3 = PEt3, PMe2Ph) with bis(iminophosphoranyl)methanes CH2(PPh2=NC6H4-4-R')2 (BIPM: 1a,R' = Me; 1b, R' = OMe) produced Pt(II) complexes, in which the BIPM ligand is N,C-coordinated: [PtX(PR3){CH-(PPh