Journal of the Chemical Society. Chemical communications p. 1669 - 1670 (1995)
Update date:2022-08-03
Topics:
Elms, F. M.
Koutsantonis, G. A.
Raston, C. L.
Thermally robust chlorogallanes, Cy3PGaH2Cl 1 and Cy3PGaHCl2 2, accessible by redistribution reactions involving Cy3PGaH3 and Cy3PGaCl3 (Cy = cyclohexyl) or 1 via anhydrous HCl reaction with Cy3PGaH3, show phosphine but not chloride-hydride exchange in aromatic solvents; treatment of 1 with a twist-boat conformation.
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