The Raction of Acetyliron 5-C5H5)Fe(CO)(PPh3)(COCH3)> with Sugar Aldehydes. New Synthesis of Deoxysugars

Article abstract of DOI:10.1016/0040-4020(94)00978-4

Aldol reactions of sugar aldehydes (5-13) with enolate 2 of racemic and both enantiomeric forms of acetyliron were investigated.The steric course of reactions depended strongly on the counterions used.High stereocontrol was achieved with the following cat