
Journal of the Chemical Society, Dalton Transactions p. 2129 - 2136 (1995)
Update date:2022-08-04
Topics:
Clegg, William
Elsegood, Mark R. J.
Farrugia, Louis J.
Lawlor, Fiona J.
Norman, Nicholas C.
Scott, Andrew J.
A range of bismuth(III) and antimony(III) thiolates, Bi(SR)3 (R = C6F5, 4-MeC6H4, 2,6-Me2C6H3 or 3,5-Me2C6H3) and Sb(SR)3 (R = 4-MeC6H4 or 3,5-Me2C6H3) has been synthesised and the structures of the two antimony complexes have been determined.Both structures reveal a trigonal-pyramidal antimony centre bonded to three thiolate groups with, for the 4-MeC6H4 complex, additional intermolecular Sb...S interactions and, for the 3,5-Me2C6H3 complex, intermolecular arene to antimony interactions.The syntheses and structures of the organotransition-metal complexes
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