1,6-Asymmetric induction in reactions between 6-hydroxy-6-methylhex-2-enyl(tributyl)stannane and aldehydes promoted by tin(IV) bromide

DOI: 10.1016/0040-4039(95)00496-Y

Source and publish data:

Tetrahedron Letters p. 3417 - 3420 (1995)

Update date:2022-07-30

Topics:

Authors:

Stanway Stanway

Thomas Thomas

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Article abstract of DOI:10.1016/0040-4039(95)00496-Y

(R)-6-Hydroxy-5-methylhex-2-enyl(tributyl)stannane 4 transmetallates on treatment with tin(IV) bromide to give an intermediate allyltin tribromide which reacts with aldehydes to give 1-substituted (Z)-6-methylhept-2-ene-1,7-diols 7 with excellent anti-1,6

Full text of DOI:10.1016/0040-4039(95)00496-Y

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