Chemistry - A European Journal p. 1342 - 1356 (1997)
Update date:2022-07-30
Topics:
Skrydstrup, Troels
Mazeas, Daniel
Elmouchir, Mohamed
Doisneau, Gilles
Riche, Claude
Chiaroni, Angele
Beau, Jean-Marie
The samarium diiodide reduction of glycosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C2-OH position leads to the stereo-specific synthesis of 1,2-cis-C-glycosides in good yield after desilylation. These reactions proceed via an
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