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1,2-cis-c-glycoside synthesis by samarium diiodide-promoted radical cyclizations

DOI: 10.1002/chem.19970030822

Source and publish data:

Chemistry - A European Journal p. 1342 - 1356 (1997)

Update date:2022-07-30

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Authors:

Skrydstrup, TroelsSkrydstrup, Troels

Mazeas, DanielMazeas, Daniel

Elmouchir, MohamedElmouchir, Mohamed

Doisneau, GillesDoisneau, Gilles

Riche, ClaudeRiche, Claude

Chiaroni, AngeleChiaroni, Angele

Beau, Jean-MarieBeau, Jean-Marie

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Article abstract of DOI:10.1002/chem.19970030822

The samarium diiodide reduction of glycosyl pyridyl sulfones bearing a silicon-tethered unsaturated group at the C2-OH position leads to the stereo-specific synthesis of 1,2-cis-C-glycosides in good yield after desilylation. These reactions proceed via an

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Full text of DOI:10.1002/chem.19970030822

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