Alkyne-niobium(I) complexes with functionalized alkynes: synthesis, structure and reactivity

DOI: 10.1016/0022-328X(95)05493-9

Source and publish data:

Journal of Organometallic Chemistry p. 29 - 36 (1995)

Update date:2022-07-29

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Authors:

Rodewald, Dieter

Schulzke, Carola

Rehder, Dieter

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Article abstract of DOI:10.1016/0022-328X(95)05493-9

The reaction between INb(CO)3(PR3)3 and diynes yielded the complexes all-trans- (PR3 = PEt3; diyne = 2,4-hexadiyne (1a), 1,5-hexadiyne (1b).PR3 = PMe2Ph, diyne = 2,6-octadiyne (1c)).Only one of the acetylenic bonds coordinates.Reactio

Full text of DOI:10.1016/0022-328X(95)05493-9

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Product name:[NbI(CO)2(P(CH₃)2C₆H₅)2((C₆H₅)2PCCP(C₆H₅)2)]

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