Angewandte Chemie - International Edition in English p. 2537 - 2539 (1996)
Update date:2022-08-03
Topics:
Steudel
Bergemann
Buschmann
Luger
A surprisingly simple, systematic route to the title compounds is achieved by ligand transfer from [Cp2TiS-NH] to the difunctional sulfanes S(n)Cl2 (n = 1,2). This should provide new impetus to sulfur nitrogen chemistry. Whereas the structure of S9NH (shown on the right) is significantly different from that of S10, the structure of S8NH resembles that of S9.
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