Tetrahedron Letters p. 4689 - 4692 (1995)
Update date:2022-08-04
Topics:
Justice, David E.
Malpass, John R.
Novel endo- 6,7-epoxy-8-azabicyclo<3.2.1>octane derivatives and the corresponding exo-analogues have been synthesised and show substantially different reactivity; the resistance of the exo-epoxides to ring opening during hydride reduction and catalytic hydrogenolysis is exploited in a total synthesis of scopine, pseudoscopine, and nor- derivatives.
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