
Journal of the Chemical Society. Chemical communications p. 1601 - 1602 (1995)
Update date:2022-08-05
Topics:
Monteil, Fanny
Alper, Howard
The germylformylation of terminal alkynes is catalysed by the zwitterionic rhodium complex, <(cod)Rh+(η6-C6H6BPh3)-> (cod = cycloocta-1,5-diene); this highly regio- and stereo-selective reaction affords (Z)-3-germylalk-2-enals in 31-82percent yield.
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