Germylformylation of Terminal Alkynes Catalysed by a Zwitterionic Rhodium(I) Complex

DOI: 10.1039/c39950001601

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1601 - 1602 (1995)

Update date:2022-08-05

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Authors:

Monteil, Fanny

Alper, Howard

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Article abstract of DOI:10.1039/c39950001601

The germylformylation of terminal alkynes is catalysed by the zwitterionic rhodium complex, <(cod)Rh+(η⁶-C6H6BPh3)-> (cod = cycloocta-1,5-diene); this highly regio- and stereo-selective reaction affords (Z)-3-germylalk-2-enals in 31-82percent yield.

Full text of DOI:10.1039/c39950001601

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