Studies in marine macrolide synthesis: Asymmetric synthesis of C1-C15/C16 subunits of swinholide A and scytophycin C

DOI: 10.1016/S0040-4039(00)73995-5

Source and publish data:

Tetrahedron Letters p. 5351 - 5354 (1993)

Update date:2022-08-03

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Authors:

Paterson, Ian

Smith, Julian D.

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Article abstract of DOI:10.1016/S0040-4039(00)73995-5

The aldehyde 8, a C_1-C₁₅ subunit of swinholide A, was prepared in 10 steps (14.5% yield, 78% ds) by starting with the asymmetric aldol reaction, 15 + 17 → 18. Conversion into the corresponding ethyl ketone 9 provides a C_1-

Full text of DOI:10.1016/S0040-4039(00)73995-5

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