SYNTHESIS AND PROPERTIES OF DERIVATIVES OF sym-TRIAZINE. 16. SYNTHESIS OF AMINE AND DIAMINE DERIVATIVES OF sym-TRIAZINE CONTAINING STERICALLY HINDERED PHENOL GROUPS FROM 6-ALKYL(ARYL)THIO-2,4-BIS(TRICHLOROMETHYL)-sym-TRIAZINE

Article abstract of DOI:10.1007/BF01169679

The reaction of 6-alkyl(aryl)thio-2,4-bis(trichloromethyl)-sym-triazines with ammonia and primary and secondary amines is studied.It is shown that, depending on the reaction conditions, the replacement of either one or both of the trichloromethyl groups takes place. 6-Alkyl-(aryl)thio-2-amino-4-trichloromethyl- and 6-alkyl(aryl)thio-2,4-diamino-sym-triazines containing sterically hindered phenol groups are synthesized.