Journal of the Chemical Society. Perkin Transactions 1 (2001) p. 396 - 401 (2002)
Update date:2022-08-03
Topics:
Miyazawa, Toshifumi
Ensatsu, Eiichi
Hiramatsu, Makoto
Yanagihara, Ryoji
Yamada, Takashi
The superiority of the carbamoylmethyl ester as an acyl donor for the α-chymotrypsin-catalysed segment condensations via the kinetically controlled approach is demonstrated in several model systems carried out in organic media with low water content. Furthermore, this approach is successfully applied to the construction of the Leu-enkephalin sequence via a 4 + 1 segment coupling.
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