Sulfur-directed 5-exo selective aryl radical cyclization onto enamide: A simple route to chilenine

DOI: 10.1016/00404-0399(50)1364-N

Source and publish data:

Tetrahedron Letters p. 6733 - 6734 (1995)

Update date:2022-08-03

Topics:: Authors:

Ishibashi, Hiroyuki

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Article abstract of DOI:10.1016/00404-0399(50)1364-N

Bu₃SnH-mediated aryl radical cyclization of the N-(o-bromoaroyl)enamine 5 took place in a 5-exo-trig manner exclusively to give isoindolone 7, which was transformed into the key intermediate 11 for the synthesis of isoindolobenzazepine alkaloid chilenine (2).

Full text of DOI:10.1016/00404-0399(50)1364-N

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Article Doi

Sulfur-directed 5-exo selective aryl radical cyclization onto enamide: A simple route to chilenine

DOI: 10.1016/00404-0399(50)1364-N

Source and publish data:

Authors:

Article abstract of DOI:10.1016/00404-0399(50)1364-N

Full text of DOI:10.1016/00404-0399(50)1364-N

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