Phytochemistry p. 1133 - 1138 (1995)
Update date:2022-08-02
Topics:
Miyazawa, Mitsuo
Nankai, Hirokazu
Kameoka, Hiromu
Microbial transformations of (+/-)-cis-nerolidol and nerylacetone were investigated using the plant pathogenic fungus, Glomerella cingulata.Both (+/-)-cis-nerolidol and nerylacetone were mainly oxidized at the remote double bond. (+/-)-cis-nerolidol was transformed into (Z)-3,7,11-trimethyl-1,6-dodecadien-3,10,11-triol while nerylacetone was transformed into (Z)-9,10-dihydroxy-6,10-dimethyl-5-undecen-2-one as the major metabolite.In addition, the biotransformation of nerylacetone resulted in hydration at the remote double bond and reduction of the carbonyl group and produced (Z)-6,10-dimethyl-5,9-undecadien-2-ol, (Z)-10-hydroxy-6,10-dimethyl-5-undecen-2-one and (Z)-6,10-dimethyl-5-undecen-2,9,10-triol.The structures of the metabolic products were determined by spectroscopic data. - Keywords: Glomerella cingulata; biotransformation; microbial transformation; plant pathogenic fungus; (+/-)-cis-nerolidol; nerylacetone.
View Morewebsite:http://www.oceanchem-group.com
Contact:86-536-8596048
Address:9th floor,Building B future Plaza, No.88.Fenghuang Street,Weifang,Shandong,China
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd
Contact:0086-10-64430626
Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Shanghai Yuanye Bio-Technology Co., Ltd.
website:http://www.shyuanye.com
Contact:+86-21-61845781
Address:Building 6, No. 465, Changta Road,Songjiang District,Shanghai,China
Shanghai Dynamic Industrial Co.,Ltd.
website:http://www.shdynamic.com
Contact:86-021 3392 6680
Address:Room 805 Information Tower, No.1403 Minsheng Road, Pudong New Area, Shanghai 200135, P. R. China
Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)
Contact:+86-027-84466317 __ +86-15387123698
Address:wuhan - china
Doi:10.1021/acs.orglett.5b00716
(2015)Doi:10.1080/15257779508010684
(1995)Doi:10.1055/s-2005-918429
(2005)Doi:10.1016/S0022-328X(00)83182-4
(1967)Doi:10.1016/0008-6215(95)00088-B
(1995)Doi:10.1016/0040-4039(95)01318-C
(1995)