Steric Control Based on Alkyl Substituents in the Sigmatropic Rearrangement of Nine-membered Allylsulfonium Ylides. A New Entry to the Stereoselective Synthesis of Elemane-type Sesquiterpenoids

DOI: 10.1039/c39940000789

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 789 - 790 (1994)

Update date:2022-08-03

Topics:

Authors:

Kido, Fusao

Yamaji, Kazuo

Sinha, Subhash C.

Yoshikoshi, Akira

Kato, Michiharu

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39940000789

The rhodium(II)-catalysed cyclisation of acyclic α-diazomalonate 1b and α-diazo-β-keto esters 1c, d give stereoselectively the highly substituted δ-lactone 3b and cyclohexanones 3c, d respectively, by <2,3>sigmatropic rearrangement via the stereocontrolle

Full text of DOI:10.1039/c39940000789

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(Z)-2,3-dimethyl-5-phenylthio-3-pentenol

Cas No:170117-66-5

R&D Labs maybe for 170117-66-5

SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China
Chengdu Cogon Bio-tech Co., Ltd.

Contact:86-28-85171192

Address:NO.52.YongFeng Rd. Chengdu,610041,P.R.China.
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Shaanxi Lighte Optoelectronics Material Co., Ltd.

Contact:+86-29-88320728-622/619/620

Address:No.55 INDUSTRY ROAD 2,XI'AN NATIONAL CIVIL AEROSPACE INDUSTRIAL PARK.XI'AN China 710065.
Arshine Pharmaceutical Co., Limited

website:http://www.cnarshine.com

Contact:0731-88503671

Address:Room 1109.Block C3, Lugu Enterprise Plaza,No.27 Wenxuan Road,Changsha National Hi-Tech Industrial Development Zone,Hunan ,P.R.China

Relevant to this article

CHIROPTICAL PROPERTIES OF STREPTONIGRIN AND A COMMENT ON ATROPISIMERISM IN HETEROCYCLIC COMPOUNDS

Doi:10.1016/S0040-4020(01)92367-1
(1981)
Rapid synthesis of [¹⁸F]SR46349B, a potent and selective 5-HT₂ receptor antagonist

Doi:10.1002/jlcr.2580360803
(1995)
Total synthesis of (+)- and (-)-K252a

Doi:10.1021/ja00146a039
(1995)
Macrobicyclic titanium(IV) complexes with C₃-symmetric synthetic peptides

Doi:10.1002/anie.199514491
(1995)
Thiazole-derived potent, highly bioavailable short duration growth hormone secretagogues

Doi:10.1016/S0960-894X(99)00286-3
(1999)
Solid support synthesis of a PNA-DNA hybrid

Doi:10.1002/recl.19951140607
(1995)

Article Doi